an accurate general method to correlate saturated vapor pressure of pure substances
نویسندگان
چکیده
in this study, a generalized equation is presented to calculate vapor pressure of pure substances as a function of reduced temperature, critical pressure, and acentric factor. with the presented model, vapor pressures have been calculated and evaluated with nist data bank for 70 pure substances for about 14000 data points, and the overall average absolute percentage deviation has been only 0.783%. also the accuracy of obtained model has been evaluated with mostly used equations and the results indicate the superiority of the proposed model against other methods used in this work.
منابع مشابه
An accurate General Method to Correlate Saturated Vapor Pressure of Pure Substances
In this study, a generalized equation is presented to calculate vapor pressure of pure substances as a function of reduced temperature, critical pressure, and acentric factor. With the presented model, vapor pressures have been calculated and evaluated with NIST data bank for 70 pure substances for about 14000 data points, and the overall average absolute percentage deviation has been only 0.78...
متن کاملEmpirical Correlations and an Artificial Neural Network Approach to Estimate Saturated Vapor Pressure of Refrigerants
The examination of available vapor pressure data in the case of the methane, ethane, propane and butane halogenated refrigerants, allowed recommendations of standard equations for this property. In this study, three new models include a general correlation; a substance-dependent correlation and an artificial neural network (ANN) approach have been developed to estimate the saturated vapor press...
متن کاملAn Accurate Correlation to Estimate Saturated Molar Volume of Liquids
There are a number of techniques available to estimate saturated-liquid molar or specific volumes or densities of liquids. In this study, a new empirical correlation is presented to calculate volume of saturated liquids as a function of critical volume, reduced temperature and acentric factor. An optimization algorithm is utilized to obtain unknown parameters of this correlation by fitting them...
متن کاملempirical correlations and an artificial neural network approach to estimate saturated vapor pressure of refrigerants
the examination of available vapor pressure data in the case of the methane, ethane, propane and butane halogenated refrigerants, allowed recommendations of standard equations for this property. in this study, three new models include a general correlation; a substance-dependent correlation and an artificial neural network (ann) approach have been developed to estimate the saturated vapor press...
متن کاملPressure Dependence of Liquid Vapor Pressure: An Improved Gibbs Prediction
A new model for the vapor phase of a pressurized liquid called "the cluster model: which is originally introduced in this work, along with an accurate equation of state for the liquid phase called the LIR, is used to derive an accurate equation for the vapor pressure of liquid as a function of external pressure. The chemical Potential of both phase have been found to be in good agreement wi...
متن کاملan accurate correlation to estimate saturated molar volume of liquids
there are a number of techniques available to estimate saturated-liquid molar or specific volumes or densities of liquids. in this study, a new empirical correlation is presented to calculate volume of saturated liquids as a function of critical volume, reduced temperature and acentric factor. an optimization algorithm is utilized to obtain unknown parameters of this correlation by fitting them...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
physical chemistry researchناشر: iranian chemical society
ISSN 2322-5521
دوره 3
شماره 1 2015
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023